Comparison of Proanthocyanidins with Different Polymerisation Degrees among Berry Skins of ‘Shiraz’, ‘Cabernet Sauvignon’, and ‘Marselan’
Abstract
Proanthocyanidins in grape berries are synthesised mainly before véraison, and very little attention ispaid to the evolution of proanthocyanidins (PAs) in grapes from véraison to harvest. The present study
focused on the changes of flavan-3-ols with different degrees of polymerisation in grape skins and the
difference in proanthocyandin composition of ‘Shiraz’, ‘Cabernet Sauvignon’ and ‘Marselan’ grapes (Vitis
vinifera L.). The results show that the content of flavan-3-ols, the percentage of prodelphinidins (%P)
and mean degree polymerisation (mDP) found in ‘Cabernet Sauvignon’ berry skins at post-véraison were
higher than those in ‘Shiraz’ and ‘Marselan’ skins. Only monomeric, dimeric, trimeric and polymeric
flavan-3-ols were detected in the three grape cultivars. Polymers with more than tenfold flavan-3-ol units
accounted for a relatively high proportion in grape berry skins, and the content in the three cultivars
declined continuously during ripening. Principal component analysis showed that proanthocyanidin
content, composition and mDP at grape harvest stage depended strongly on grape cultivar. This study
provides some useful information for understanding the accumulation of PAs during berry maturation
and this information can be used to improve wine quality.
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